Precipitate flotation of copper as the sulfide,using recyclable amphoteric surfactants

An experimental study was made to identify surfactants which are effective for removal of copper from dilute aqueous solution (100–500 ppm) by precipitate flotation as the sulfide, and which at the same time can be recovered from the CuS product for recycle. Batch flotation experiments confirmed that a cationic surfactant was necessary for flotation of CuS from such dilute suspensions; however, no satisfactory way could be found for recovering cationic surfactants from the CuS. This led to consideration of amphoteric surfactants, which are cationic at low pH and anionic at high pH. It was found that a change to negative, rather than simply neutral, charge was required for efficient surfactant recovery. It was further found, through the assistance of experiments in which the CuS suspension was agitated with solvents, that certain functional groups which interact chemically with the CuS surface should also be absent from the surfactant molecule. Following this logic, Amphoterge K-2 (Lonza Chemical Co.) was identified as a suitable surfactant, provided CuS was precipitated with S^2? in excess. Tests established that 95% of adsorbed Amphoterge K-2 could be recovered by raising the pH to 11 and boiling the suspension for one hour, followed by decanting. Surfactant thus recovered was effective in a second flotation test. Foamate solids settled rapidly; such behavior would help reduce the consumption of chemicals for the pH change.Column flotation studies were made using Amphoterge K-2 for removal of Cu²⁺ present at 100 ppm and pH = 2. High removals of CuS could be obtained at concentrations of surfactant above about 25 ppm, for which conditions a substantial fraction of the surfactant remains in solution rather than being adsorbed onto the CuS. The recovery of CuS would be improved by introducing the surfactant in a separate feed, below the feed of CuS suspension. Adding some surfactant in the CuS feed, as well as in a lower feed, gave an even better recovery of CuS (99.8%) at sufficiently high surfactant loadings.     

Preprocessing of gravity gradients at the GOCE high-level processing facility

One of the products derived from the gravity field and steady-state ocean circulation explorer (GOCE) observations are the gravity gradients. These gravity gradients are provided in the gradiometer reference frame (GRF) and are calibrated in-flight using satellite shaking and star sensor data. To use these gravity gradients for application in Earth scienes and gravity field analysis, additional preprocessing needs to be done, including corrections for temporal gravity field signals to isolate the static gravity field part, screening for outliers, calibration by comparison with existing external gravity field information and error assessment. The temporal gravity gradient corrections consist of tidal and nontidal corrections. These are all generally below the gravity gradient error level, which is predicted to show a 1/f behaviour for low frequencies. In the outlier detection, the 1/f error is compensated for by subtracting a local median from the data, while the data error is assessed using the median absolute deviation. The local median acts as a high-pass filter and it is robust as is the median absolute deviation. Three different methods have been implemented for the calibration of the gravity gradients. All three methods use a high-pass filter to compensate for the 1/f gravity gradient error. The baseline method uses state-of-the-art global gravity field models and the most accurate results are obtained if star sensor misalignments are estimated along with the calibration parameters. A second calibration method uses GOCE GPS data to estimate a low-degree gravity field model as well as gravity gradient scale factors. Both methods allow to estimate gravity gradient scale factors down to the 10⁻³ level. The third calibration method uses high accurate terrestrial gravity data in selected regions to validate the gravity gradient scale factors, focussing on the measurement band. Gravity gradient scale factors may be estimated down to the 10⁻² level with this method.     

Diluvialgeologie und Klima

Ohne Zusammenfassung     

Development and validation of a finite element morphological model for shallow water basins

Recognising the importance of understanding sediment dynamics to evaluate the status of a coastal lagoon environment, this work has been focused on the investigation of the hydrodynamic and sediment transport processes occurring in such basins. In order to describe the lagoon system, a modelling approach combining hydrodynamics, waves and sediment dynamics has been developed. The framework of the numerical model consists of a finite element hydrodynamic model, a third generation finite element spectral wave model and a sediment transport and morphodynamic model for both cohesive and non-cohesive sediments. The model adopts the finite element technique for spatial integration, which has the advantage to describe more accurately complicated bathymetry and irregular boundaries for shallow water areas. The developed model has been applied to test cases and to a very shallow tidal lagoon, the Venice Lagoon, Italy. Numerical results show good agreement with water level, waves and turbidity measurements collected in several monitoring stations inside the Lagoon of Venice. Such a model represents an indispensable tool in analysing coastal problems and assessing morphological impacts of human interference.     

Shock barometry of the Siljan impact structure,Sweden

Abstract– The Siljan impact structure in Sweden is the largest confirmed impact structure in Western Europe. Despite this, the structure has been poorly studied in the past, and detailed studies of shock metamorphic features in the target lithologies are missing. Here, we present the results of a detailed systematic search for shock metamorphic features in quartz grains from 73 sampled localities at Siljan. At 21 localities from an area approximately 20 km in diameter located centrally in the structure, the orientations of 2851 planar deformation feature sets in 1179 quartz grains were measured. Observations of shatter cones outside of the zone with shocked quartz extend the total shocked area to approximately 30 km in diameter. The most strongly shocked samples, recording pressures of up to 20 GPa, occur at the very central part of the structure, and locally in these samples, higher pressures causing melting conditions in the affected rocks were reached. Pressures recorded in the studied samples decrease outwards from the center of the structure, forming roughly circular envelopes around the proposed shock center. Based on the distribution pattern of shocked quartz at Siljan, the original transient cavity can be estimated at approximately 32–38 km in diameter. After correcting for erosion, we conclude that the original rim to rim diameter of the Siljan crater was somewhere in the size range 50–90 km.     

A 3‐D study of mineral inclusions in chromite from ordinary chondrites using synchrotron radiation X‐ray tomographic microscopy—Method and applications

Abstract– A method is described for imaging in 3‐D the interiors of meteoritic chromite grains and their inclusions using synchrotron radiation X‐ray tomographic microscopy. In ordinary chondrites, chromite is the only common mineral that survives long‐term weathering on Earth. Information about the silicate matrix of the original meteorite, however, can be derived from mineral inclusions preserved in the protecting chromite. The inclusions are crucial in the classification of fossil meteorites as well as sediment‐dispersed chromite grains from decomposed meteorites and larger impacts, as these are used for characterizing the past influx of material to Earth, but have previously been difficult to locate. The method is non‐destructive and time efficient for locating inclusions. The method allowed quantitative and morphological studies of both host chromite grains and inclusions in three dimensions. The study of 385 chromite grains from eight chondrites (H4–6, L4–6, LL4, LL6) reveals that inclusions are abundant and equally common in all samples. Almost two‐thirds of all chromite grains contain inclusions, regardless of group and type. The study also shows that the size of the inclusions and the host chromite grains, as well as the number of inclusions, within the host chromite grains vary with petrographic type. Thus, the petrographic type of the host of a suite of chromite grains can be determined based solely on inclusion content. The study also revealed that the amount of fractures in the host chromite can be correlated to previously assigned shock stages for the various chondrites. The study has thus shown that the features and inclusions of fossil chromite grains can give similar information about a former host meteorite as do studies of an unweathered whole meteorite, meaning that this technique is essential in the studies of ancient meteorite flux to Earth.     

The lunar rock and mineral characterization consortium: Deconstruction and integrated mineralogical,petrologic, and spectroscopic analyses of mare basalts

The lunar rock and mineral characterization consortium (LRMCC) has conducted coordinated mineralogy/petrography/spectroscopy analyses of a suite of pristine lunar basalts. Four basalt slabs (two low‐Ti, two high‐Ti) and paired thin sections were analyzed. Thin sections were analyzed for mineralogy/petrography, while the slabs were used to prepare particulate separates of major mineral phases and bulk samples. Mineral separates and particulate bulk samples were crushed to controlled grain sizes and their reflectance spectra measured in the NASA RELAB at Brown University. The resulting data set provides an essential foundation for spectral mixing models, offers valuable endmember constraints for space weathering analyses, and represents critical new ground truth results for lunar science and exploration efforts.     

Near‐infrared spectra of clinopyroxenes: Effects of calcium content and crystal structure

Abstract– Pyroxenes are among the most common minerals in the solar system and are ideally suited for remote geochemical analysis because of the sensitivity of their distinctive spectra to mineral composition. Fe²⁺ is responsible for the dominant pyroxene absorptions in the visible and near‐infrared, but substitutions of other cations such as Ca²⁺ change the crystal structure and site geometries and thus the crystal field splitting energies of the Fe cations. To define spectral systematics resulting from major pyroxene cations (Ca²⁺, Mg²⁺, and Fe²⁺), we focus on a suite of pyroxenes synthesized with only Ca²⁺, Mg²⁺, and Fe²⁺ in the two octahedral sites, specifically examining the effect of Ca²⁺ on pyroxene absorption bands. The modified Gaussian model is used to deconvolve pyroxene spectra into component bands that can then be linked directly to crystal field absorptions. In orthopyroxenes and low‐Ca clinopyroxenes, Ca²⁺‐content has a strong and predictable effect on the positions of the absorption bands. At a threshold of Wo₃₀, the crystal field environment stagnates and the M2 bands cease to change significantly as more Ca²⁺ is added. At Wo₅₀, when most of the M2 sites are filled by Ca²⁺, band positions do not change drastically, although the presence and strengths of the 1 and 2 μm bands are affected by even trace amounts of Fe²⁺ in the M2 site. It is thus apparent that next‐nearest neighbors and the distortions they impose on the pyroxene lattice affect the electronic states around the Fe²⁺ cations and control absorption band properties.